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The implementation of emission standards has brought significant reductions in vehicle emissions in the EU, but road transport is still a major source of air pollution. Future emission standards will aim at making road vehicles as clean as possible under a wide range of driving conditions and throughout their complete lifetime. The current paper presents the methodology followed by the Consortium for ultra LOw Vehicle Emissions (CLOVE) to support the preparation of the Euro 7 proposal. As a first step, the emission performance of the latest-technology vehicles under various driving conditions was evaluated. Towards this direction, an emissions database was developed, containing data from a wide range of tests, both within and beyond the current RDE boundaries.

NH₃/urea SCR is a very effective and widely used technology for the abatement of NOx from diesel exhaust. The SCR mechanism is well understood and the catalyst behavior can be predicted by mathematical models - as long as operation above the temperature limit for AdBlue® injection is considered. The behavior below this level is less understood. During the first seconds up to minutes after cold start, complete NOx abatement can be observed over an SCR catalyst in test bench experiments, together with a significant increase in temperature after the converter (ca. 100 K). In this work these effects have been investigated over a monolith Cu-zeolite SCR catalyst. Concentration step experiments varying NO, NO₂ and H₂O have been carried out in lab scale, starting from room temperature. Further, the interaction of C₃H₆ and CO with NOx over the SCR has been investigated.

While the optimization of the internal combustion engine (ICE) remains a very important topic, alternative fuels are also expected to play a significant role in the reduction of CO2 emissions. High energy densities and handling ease are their main advantages amongst other energy carriers. Ammonia (NH3) additionally contains no carbon and has a worldwide existing transport and storage infrastructure. It could be produced directly from renewable electricity, water and air, and is thus currently considered as a smart energy carrier and combustion fuel. However, ammonia presents a low combustion intensity and the risk of elevated nitrogen-based emissions, thus rendering in-depth investigation of its suitability as an ICE fuel necessary. In the present study, a recent single-cylinder spark-ignition engine is fueled with gaseous ammonia/hydrogen/air mixtures at various hydrogen fractions, equivalence ratios and intake pressures.

Ammonia is now recognized as a very serious asset in the context of the hydrogen energy economy, thanks to its non-carbon nature, competitive energy density and very mature production, storage and transport processes. If produced from renewable sources, its use as a direct combustion fuel could participate to the flexibility in the power sector as well as help mitigating fossil fuel use in certain sectors, such as long-haul shipping. However, ammonia presents unfavorable combustion properties, requiring further investigation of its combustion characteristics in practical systems. In the present study, a modern single-cylinder spark-ignition engine is fueled with gaseous ammonia/air mixtures at various equivalence ratios and intake pressures. The results are compared with methane/air and previous ammonia/hydrogen/air measurements, where hydrogen is used as combustion promoter. In-cylinder pressure and exhaust concentrations of selected species are measured and analyzed.

Predictive combustion models are useful tools towards the development of clean and efficient engines operating with alternative fuels. This work intends to validate two different combustion models on compression-ignition engines fueled with Dimethyl Ether. Both approaches give a detailed characterization of the combustion kinetics, but they substantially differ in how the interaction between fluid-dynamics and chemistry is treated. The first one is single-flamelet Representative Interactive Flamelet, which considers turbulence-kinetic interaction but cannot correctly describe the stabilization of the flame. The second, named Tabulated Well Mixed, correctly accounts for local flow and mixture conditions but does not consider interaction between turbulence and chemistry. An experimental campaign was carried out on a heavy-duty truck engine running on DME at a constant load considering trade-off of EGR and SOI.

The abatement of carbon dioxide and pollutant emissions on motorbike spark-ignition (SI) engines is a challenging task, considering the small size, the low cost and the high power-to-weight ratio required by the market for such powertrain. In this context, the passive pre-chamber (PPC) technology is an attractive solution. The combustion duration can be reduced by igniting the air-fuel mixture inside a small volume connected to the cylinder, unfolding the way to high engine efficiencies without penalization of the peak performance. Moreover, no injectors are needed inside the PPC, guaranteeing a cheap and fast retrofitting of the existing fleet. In this work, a 3D computational fluid dynamics (CFD) investigation is carried out over an experimental configuration of motorbike SI engine, operated at fixed operating conditions with both traditional and PPC configurations.

The reduction of the catalyst light-off time at the engine cold start represents a key factor for the pollutant emissions control from vehicles tested on homologation cycles and real drive conditions. The adoption of heating strategies to increase the temperature of the catalytic substrate in the early phase of the engine start is regarded as a promising solution. The present study focuses on the application of electrical heated catalyst (EHC) in an after-treatment line for a spark-ignition gasoline engine. The analysis is carried out by means of an advanced CFD framework, which includes the modeling of catalytic reactions in the substrates and accounts for the thermal evolution of all the components included in the after-treatment system.

Stoichiometric natural gas (CNG) engines are an attractive solution for heavy-duty vehicles considering their inherent advantage in emitting lower CO2 emissions compared to their Diesel counterparts. Additionally, their aftertreatment system can be simpler and less costly as NOx reduction is handled simultaneously with CO/HC oxidation by a Three-Way Catalyst (TWC). The conversion of methane over a TWC shows a complex behavior, significantly different than non-methane hydrocarbons in stoichiometric gasoline engines. Its performance is maximized in a narrow A/F window and is strongly affected by the lean/rich cycling frequency. Experimental and simulation results indicate that lean-mode efficiency is governed by the palladium’s oxidation state while rich conversion is governed by the gradual formation of carbonaceous compounds which temporarily deactivate the active materials.

The target of the upcoming automotive emission regulations is to promote a fast transition to near-zero emission vehicles. As such, the range of ambient and operating conditions tested in the homologation cycles is broadening. In this context, the proposed work aims to thoroughly investigate the potential of post-oxidation phenomena in reducing the light-off time of a conventional three-way catalyst. The study is carried out on a turbocharged four-cylinder gasoline engine by means of experimental and numerical activities. Post oxidation is achieved through the oxidation of unburned fuel in the exhaust line, exploiting a rich combustion and a secondary air injection dedicated strategy. The CFD methodology consists of two different approaches: the former relies on a full-engine mesh, the latter on a detailed analysis of the chemical reactions occurring in the exhaust line.

Air pollution is a significant environmental issue, and exhaust emissions from internal combustion engines are one of the primary sources of harmful pollutants. The transportation sector, which includes road vehicles, contributes to a large share of these emissions. In Europe, the latest emission legislation (Euro 7) proposes more stringent limits and testing conditions for vehicle emissions. To meet these limits, the automotive industry is actively developing innovative exhaust emission-control technologies. With the growing prevalence of electrification, internal combustion engines are subject to continuous variations in load and engine speed, including phases where the engine is switched off. The result is an operating condition characterized by successive cold starts. In this context, the challenge in coping with the emission limits is to minimize the light-off time and prevent fast light-out conditions during idling or city driving.

In 2023, the European Union set more ambitious targets for reducing greenhouse gas emissions from passenger cars: the new fleet-wide average targets became 93.6 g/km for 2025, 49.5 g/km in 2030, going to 0 in 2035. One year away from the 2025 target, this study evaluates what contribution to CO2 reduction was achieved from new conventional vehicles and how to interpret forecasts for future efficiency gains. The European Commission’s vehicle efficiency cost-curves suggest that optimal technology adoption can guarantee up to 50% CO2 reduction by 2025 for conventional vehicles. Official registration data between 2013 and 2022, however, reveal only an average 14% increase in fuel efficiency in standard combustion vehicles, although reaching almost 23% for standard hybrids. The smallest gap between certified emissions and best-case scenarios is of 14 g/km, suggesting that some manufacturers’ declared values are approaching the optimum.

The proposed Euro 7 emission standard foresees that the emission behaviour of Euro 7 vehicles is monitored via an on-board monitoring (OBM) system. In Euro 7 vehicles, OBM systems will monitor the emissions of nitrogen oxides (NOX), ammonia (NH3) and particulate matter (PM) for every trip through a combination of measured and modelled data. Sensors employed to support on-board diagnostics (OBD) in current vehicles may be used to support OBM. According to the Euro 7 OBM concept presented in this paper, OBM will serve a dual purpose: the first is to warn the user of a vehicle about the need to perform repairs on the engine or the pollution control systems when these are needed. If these repairs are not performed in a timely manner, the OBM system will be able to ultimately prevent engine restart, akin to the existing low-reagent driver warning system in some compression ignition vehicles. The second purpose of OBM is to monitor the compliance of vehicle types with the emission limits.